Journal
DALTON TRANSACTIONS
Volume 45, Issue 6, Pages 2436-2439Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04606h
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- Air Force Office of Scientific Research through the MURI program under AFOSR Award [FA9550-10-1-0572]
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A series of [Cp*Ir-III(R-bpy)Cl]Cl (R-bpy = 4,4'-di-R-2,2'-bipyridine; R = CF3, H, Me, tBu, OMe) complexes was prepared and studied for catalytic formic acid disproportionation. The relationship between the electron donating strength of the bipyridine substituents and methanol production of the corresponding complexes was analyzed; the unsubstituted (R = H) complex was the most selective for methanol formation.
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