4.7 Article

Cunning metal core: efficiency/stability dilemma in metallated porphyrin based light-emitting electrochemical cells

Journal

DALTON TRANSACTIONS
Volume 45, Issue 34, Pages 13284-13288

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt02293f

Keywords

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Funding

  1. excellence cluster Engineering of Advanced Materials (EAM)
  2. Fonds der Chemischen Industrie (VCI) [FP7-REGPOT-2008-1]
  3. BIOSOLENUTI [229927]
  4. project Implementing advanced interfacial engineering strategies for highly efficient hybrid solar cells (IMAGINE-HYSOL)
  5. European Social Fund (ESF) and National Resources

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The syntheses, photophysical/electrochemical characterizations of different metallated porphyrins - i.e., Zn2+, Pt2+, Pd2+, and Sn4+ porphyrins - as well as their first application in light-emitting electrochemical cells are provided. A direct comparison demonstrates that depending on the metallation either efficient (Pt-por) or stable (Zn-por) devices are achieved, demonstrating that the choice of the metal core is a key aspect for future developments.

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