Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 13, Pages 7227-7233Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202016085
Keywords
defect passivation; dopant-free hole-transporting materials; inverted perovskite solar cells; non-radiative recombination
Categories
Funding
- Natural Science Foundation of China [51873160, 21975085]
- APRC Grant of the City University of Hong Kong [9380086, 9610421]
- Innovation and Technology Support Programme [ITS/497/18FP, GHP/021/18SZ]
- Guangdong-Hong Kong-Macao joint laboratory of optoelectronic and magnetic 6bal materials [2019B121205002]
- ECS [CityU 21301319]
- Collaborative Research Fund grant from the Research Grants Council of Hong Kong [C5037-18G]
- Natural Science Foundation of Guangdong Province [2019A1515010761]
- Guangdong Major Project of Basic and Applied Basic Research [2019B030302007]
- Air Force Office of Scientific Research [FA9550-18-1-0046]
Ask authors/readers for more resources
This study presents a new pyridine-based polymer hole-transporting material, PPY2, that can simultaneously reduce non-radiative recombination processes in inverted perovskite solar cells. By using PPY2, the research has successfully improved the performance metrics of PVSCs and achieved good long-term photostability.
Currently, the performance improvement for inverted perovskite solar cells (PVSCs) is mainly limited by the high open circuit voltage (V-OC) loss caused by detrimental non-radiative recombination (NRR) processes. Herein, we report a simple and efficient way to simultaneously reduce the NRR processes inside perovskites and at the interface by rationally designing a new pyridine-based polymer hole-transporting material (HTM), PPY2, which exhibits suitable energy levels with perovskites, high hole mobility, effective passivation of the uncoordinated Pb2+ and iodide defects, as well as the capability of promoting the formation of high-quality polycrystalline perovskite films. In absence of any dopants, the inverted PVSCs using PPY2 as the HTM deliver an encouraging PCE up to 22.41 % with a small V-OC loss (0.40 V), among the best device performances for inverted PVSCs reported so far. Furthermore, PPY2-based unencapsulated devices show an excellent long-term photostability, and over 97 % of its initial PCE can be maintained after one sun constant illumination for 500 h.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available