Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

The concepts of aromaticity and antiaromaticity have a long history, and countless demonstrations of these phenomena have been made with molecules based on elements from the p, d, and f blocks of the periodic table. In contrast, the limited oxidation-state flexibility of the s-block metals has long stood in the way of their participation in sophisticated pi-bonding arrangements, and truly antiaromatic systems containing s-block metals are altogether absent or remain poorly defined. Using spectroscopic, structural, and computational techniques, we present herein the synthesis and authentication of a heterocyclic compound containing the alkaline earth metal beryllium that exhibits significant antiaromaticity, and detail its chemical reduction and Lewis-base-coordination chemistry.

Automated summary

The research focuses on synthesizing and authenticating a heterocyclic compound containing the alkaline earth metal beryllium that exhibits significant antiaromaticity, and delving into its chemical properties in terms of reduction and Lewis-base-coordination chemistry using spectroscopic, structural, and computational techniques.