Journal
DALTON TRANSACTIONS
Volume 45, Issue 32, Pages 12649-12652Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt02535h
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [24350029, 2406, 24107004]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - World Premier International Research Center Initiative (WPI), MEXT, Japan
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [24107004, 14J06604, 15H03786] Funding Source: KAKEN
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The water oxidation (WO) activity of a chlorinated cobalt tetraphenylporphyrin (CoClPS), possessing Cl atoms on the 2,6-positions of the aryl groups, shows higher resistance to attack by singlet oxygen, in situ generated during photochemical WO using Ru(bpy)(3)(2+) and S2O82- with the turnover frequency (TOF) and turnover number (TON) reaching 1.7 s(-1) and 836, respectively.
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