Journal
DALTON TRANSACTIONS
Volume 45, Issue 8, Pages 3251-3255Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04027b
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Funding
- Spanish MINECO/FEDER [CTQ2013-45518-P]
- DFG Excellence 'Engineering of Advanced Materials' (EAM)
- Fonds der Chemischen Industrie (FCI)
- UR
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We report two unprecedent alkynyl bridging cyclometalated clusters [Ir2M2(ppy)(4)(mu-C CC6H4-OMe3)(4)] where M is Ag (2) and Cu (3), which display distinctive luminescence properties. While 2 features a green phosphorescence/electroluminescence nature located at the ppy ligands ((LC)-L-3), 3 shows an orange emission confined to the metals and alkynyl groups having a mixed L-3'C/L-3' MCT/(MMCT)-M-3 (L' = alkynyl) nature.
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