4.7 Article

A novel method for the synthesis of solvent-free Mg(B3H8)2

Journal

DALTON TRANSACTIONS
Volume 45, Issue 9, Pages 3687-3690

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04517g

Keywords

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Funding

  1. National Natural Science Foundation of China [51431001, 51271078, U120124]
  2. GDUPS
  3. Guangdong Natural Science Foundation [2014A030311004]
  4. International Science & Technology Cooperation Program of China [2015DFA51750]
  5. Swiss National Science Foundation (SNFS) [150638]

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This communication presents a novel and solvent-free method to synthesise Mg(B3H8)(2) via the gas-solid reaction between B2H6 and Mg2NiH4, which overcomes the limitations of wet chemical methods requiring solvent removal.

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