Journal
DALTON TRANSACTIONS
Volume 45, Issue 10, Pages 4283-4288Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03621f
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Funding
- French National Agency for Research ANR MODS [ANR-12-BS10-0005]
- Institut Universitaire de France
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The structural behaviour under mechanical stimuli of two metal organic frameworks, UiO-66(Zr) and MIL-125(Ti) and their amino-functionalized derivatives has been investigated by high-pressure powder X-ray diffraction up to 3.5 GPa. All these solids showed a gradual pressure-induced reversible decrease of their crystallinity and UiO-66(Zr)_NH2 material has been revealed as one of the most resilient MOFs reported so far corresponding to a very high bulk modulus. The mechanical behaviors of these MOFs have been correlated to their chemical and geometric features including the metal-oxygen coordination number, the nature of the organic linker, the porosity as well as their crystal density.
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