Journal
DALTON TRANSACTIONS
Volume 45, Issue 14, Pages 6088-6093Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03815d
Keywords
-
Categories
Funding
- National Nature Science Foundation of China [21372048]
- Shanghai Science and Technology Committee (Shanghai Rising-Star Program) [13QA1400500]
- Fudan University
Ask authors/readers for more resources
Two 2,4,6-tris(trifluoromethyl)phenyl-substituted 2-(lutidinyl)organoboranes (5a and 5b) were prepared. These complexes can function as intramolecular vicinal B/N frustrated Lewis pairs to heterolytically activate dihydrogen. When these complexes were treated with HBpin, two different reaction pathways took place. Whereas the reaction between 5a and HBpin affords a formal ligand-redistribution product, the reaction of 5b with HBpin leads to a dearomative dehydroborylation product.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available