Journal
DALTON TRANSACTIONS
Volume 45, Issue 34, Pages 13289-13293Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01554a
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Funding
- Knut and Alice Wallenberg Foundation
- Swedish Research Council [621-2013-4872]
- Carl Trygger Foundation
- DFG (Metal Sites in Biomolecules: Structures, Regulation and Mechanisms) [IRTG 1422]
- Swedish Energy Agency
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The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the di-nucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)(3)](3+).
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