Journal
DALTON TRANSACTIONS
Volume 45, Issue 7, Pages 3063-3069Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04316f
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Funding
- Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-08ER46519]
- German Academic Exchange Service (DAAD)
- research cluster SusChemSys
- European Regional Development Fund (ERDF)
- state of North Rhine-Westphalia, Germany, under the Operational Programme Regional Competitiveness and Employment
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A series of unprecedented crown ether- and thiacrown ether-derivatized benzene dicarboxylic acid (H(2)bdc) ligands has been synthesized and incorporated into the prototypical isoreticular metal-organic framework (IRMOF) and UiO-66 materials. In the case of UiO-66, only MOFs comprised from a mixed-ligand composition, requiring both unsubstituted bdc and crown ether containing ligands, could be prepared. These are among the few ligand derivatives, and resulting MOFs, that incorporate a macrocyclic group directly on the bdc ligand, providing a new, modular platform for exploring new supramolecular and coordination chemistry within MOFs.
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