Journal
AICHE JOURNAL
Volume 67, Issue 7, Pages -Publisher
WILEY
DOI: 10.1002/aic.17215
Keywords
graphene oxide; membrane; water transport channel; water‐ ethanol separation; zwitterion
Categories
Funding
- National Natural Science Foundation of China [21921006, 22038006, 51861135203, 51972169, 91934303]
- Innovative Research Team Program by the Ministry of Education of China [IRT_17R54]
- Topnotch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
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A new strategy of constructing exclusive and fast water channels in graphene oxide (GO) membranes was proposed to achieve high-performance water-ethanol separation. By utilizing the synergy between zwitterion-functionalized GO and hydrophilic polyelectrolyte, the ordered and stable channels formed in the membrane possess high-density ionic hydrophilic groups, allowing for efficient separation of strong-coupling mixtures like water-ethanol.
Graphene oxide (GO) membranes have shown great prospects as the next-generation membranes to tackle many challenging separation issues. However, the employment of GO membranes remains difficult for the precise separation of molecules with strong coupling effect and small size discrepancy such as water-ethanol. Herein, a new strategy of constructing exclusive and fast water channels in GO membrane was proposed to achieve high-performance water-ethanol separation via the synergy between zwitterion-functionalized GO and hydrophilic polyelectrolyte. The as-formed ordered and stable channels possess high-density ionic hydrophilic groups, which benefit from inhibiting the strong coupling between water and ethanol, facilitating the fast permeation of water molecules while suppressing ethanol molecules. As a result, the ultrathin GO-based membrane acquires exceptionally high separation performance with a flux of 3.23 kg/m(2) h and water-ethanol separation factor of 2,248 when separating water-ethanol (10 wt%/90 wt%) mixture at 343 K. This work paves a feasible way to construct 2D channels for the high-efficiency separation of strong-coupling mixtures.
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