Journal
DALTON TRANSACTIONS
Volume 45, Issue 4, Pages 1331-1334Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04228c
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Funding
- Naito Foundation
- JSPS [26105003]
- Grants-in-Aid for Scientific Research [16H04121, 26105003] Funding Source: KAKEN
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A novel light-active Pd complex having a BINAP ligand with 2-naphthyl substituents on the phosphines was synthesized and characterized. The complex showed good polymerization activity toward 4-methoxystyrene during irradiation (lambda = 395 nm) and the reaction progress can be controlled by ON-OFF switching of the light source. Mechanistic investigations strongly suggest a coordination-insertion mechanism.
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