Journal
DALTON TRANSACTIONS
Volume 45, Issue 44, Pages 17606-17609Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt03630a
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Funding
- NSF of China [21171168, 21225104, 21233009, 21301175, 21571020, 91422303]
- NSF of Fujian Province [2015J01071]
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The discovery of novel materials with very low thermal conductivity is paramount to improving the efficiency of thermoelectric devices. Here we present a series of quaternary semiconducting tellurides AX(4)(II)X(5)(III)Te(12) (A = Rb, Cs; X-II = Mn, Zn, Cd; X-III = Ga, In) with three-dimensional (3D) diamond-like frameworks (DLFs) and they exhibit a very low thermal conductivity (ca. 0.26-0.42 W m(-1) K-1) around 800 K.
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