Journal
DALTON TRANSACTIONS
Volume 45, Issue 17, Pages 7226-7230Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01015f
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Funding
- NSERC (Canada)
- DAAD (Germany)
- Department of Energy Basic Energy Sciences [DE-FG02-07ER46475]
- University of Western Ontario
- King Abdul Aziz University (Saudi Arabia)
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The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.
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