Journal
DALTON TRANSACTIONS
Volume 45, Issue 6, Pages 2404-2408Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04022a
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- DFG
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Deeper investigations on the silylation reaction of the Ge-9(4-) Zintl anion are provided. The reaction of K4Ge9 with two equivalents of ClHyp (Hyp = Si(SiMe3)(3)) gives the metalloid cluster compound [Ge-9(Hyp)(2)](2-). Subsequent reactions with this compound give access to the first mixed trisubstituted metalloid cluster [Ge-9(Hyp)(2)( Hyp(Ph3))](-) (HypPh(3) = Si(SiMe3)(2)(SiPh3)), opening a way to a variety of mixed substituted Ge-9 clusters for future investigations.
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