Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 363, Issue 5, Pages 1346-1351Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202001423
Keywords
Ring-Opening; Selenocyanation; Heterocycles; Elemental Selenium; Radical
Categories
Funding
- National Natural Science Foundation of China [21901187, 21472140]
- Natural Science Foundation of Zhejiang Province [LY21B020001]
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A catalyst and additive-free strategy for selective ring-opening selenocyanation of saturated heterocycles has been developed, yielding a series of aliphatic selenocyanates and selenaheterocycles using elemental selenium and TMSCN. In the case of unprotected unstrained N-heterocycles, the reactions produce ammonium selenonitriles which are proven to be efficient selenonitrile reagents.
A catalyst and additive-free strategy for selective ring-opening selenocyanation of saturated heterocycles with elemental selenium and TMSCN is developed, affording a series of aliphatic selenocyanates and selenaheterocycles. In the case of unprotected unstrained N-heterocycles, the reactions offer ammonium selenonitriles that prove to be an efficient selenonitrile reagent.
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