4.8 Review

Soft Ferroelectrics Enabling High-Performance Intelligent Photo Electronics

Journal

ADVANCED MATERIALS
Volume 33, Issue 47, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202004999

Keywords

non-centrosymmetric molecular assemblies; nonvolatile photoelectronic devices; organic ferroelectrics; organic-inorganic ferroelectrics; programmable electric fields; soft ferroelectrics

Funding

  1. Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2018M3D1A1058536]
  2. National Research Foundation of Korea (NRF) - Korean government (MEST) [2020R1A2B5B03002697]

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Soft ferroelectrics based on organic and organic-inorganic hybrid materials are gaining popularity among researchers due to their electrically programmable and remnant polarization, leading to the development of flexible, foldable, and stretchable nonvolatile memories. These materials are seen as playing a crucial role in human-connected electronics, particularly in devices requiring precise programmable electric fields, such as tactile sensors, synaptic devices, displays, photodetectors, and solar cells, for enhanced human-machine interaction, safety, and sustainability. This review presents a comprehensive overview of recent advancements in soft ferroelectric materials and their potential applications in intelligent human-connected electronics.
Soft ferroelectrics based on organic and organic-inorganic hybrid materials have gained much interest among researchers owing to their electrically programmable and remnant polarization. This allows for the development of numerous flexible, foldable, and stretchable nonvolatile memories, when combined with various crystal engineering approaches to optimize their performance. Soft ferroelectrics have been recently considered to have an important role in the emerging human-connected electronics that involve diverse photoelectronic elements, particularly those requiring precise programmable electric fields, such as tactile sensors, synaptic devices, displays, photodetectors, and solar cells for facile human-machine interaction, human safety, and sustainability. This paper provides a comprehensive review of the recent developments in soft ferroelectric materials with an emphasis on their ferroelectric switching principles and their potential application in human-connected intelligent electronics. Based on the origins of ferroelectric atomic and/or molecular switching, the soft ferroelectrics are categorized into seven subgroups. In this review, the efficiency of soft ferroelectrics with their distinct ferroelectric characteristics utilized in various human-connected electronic devices with programmable electric field is demonstrated. This review inspires further research to utilize the remarkable functionality of soft electronics.

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