4.8 Review

Recent Progress in Solution-Based Metal Oxide Resistive Switching Devices

Journal

ADVANCED MATERIALS
Volume 33, Issue 7, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202004328

Keywords

memristors; metal oxide thin films; resistive random‐ access memories; resistive switching; solution‐ based technology

Funding

  1. National Funds through FCT-FundacAo para a Ciencia e Tecnologia, I.P. [UIDB/50025/2020]
  2. FCT/MCTES [SFRH/BD/116047/2016, PTDC/NAN-MAT/30812/2017]
  3. European Institute of Innovation and Technology (EIT RawMaterials, Horizon 2020) Supersmart, Scale-Up of Printed Electronics [17161]
  4. ERC AdG grant from the project DIGISMART [787410]
  5. IDS-FunMat-INNO project FPA2016/EIT/EIT RawMaterials Grant Agreement [15015]
  6. Fundação para a Ciência e a Tecnologia [SFRH/BD/116047/2016, PTDC/NAN-MAT/30812/2017] Funding Source: FCT

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Metal oxide resistive switching memories are crucial for the requirements of the Internet of Things, and solution-based devices offer advantages such as high flexibility and low cost. These devices are emergent and promising non-volatile memories for future electronics.
Metal oxide resistive switching memories have been a crucial component for the requirements of the Internet of Things, which demands ultra-low power and high-density devices with new computing principles, exploiting low cost green products and technologies. Most of the reported resistive switching devices use conventional methods (physical and chemical vapor deposition), which are quite expensive due to their up-scale production. Solution-processing methods have been improved, being now a reliable technology that offers many advantages for resistive random-access memory (RRAM) such as high versatility, large area uniformity, transparency, low-cost and a simple fabrication of two-terminal structures. Solution-based metal oxide RRAM devices are emergent and promising non-volatile memories for future electronics. In this review, a brief history of non-volatile memories is highlighted as well as the present status of solution-based metal oxide resistive random-access memory (S-RRAM). Then, a focus on describing the solution synthesis parameters of S-RRAMs which induce a massive influence in the overall performance of these devices is discussed. Next, a precise analysis is performed on the metal oxide thin film and electrode interface and the recent advances on S-RRAM that will allow their large-area manufacturing. Finally, the figures of merit and the main challenges in S-RRAMs are discussed and future trends are proposed.

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