Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 31, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202009457
Keywords
hybrid double perovskites; lead-free perovskites; molecular ferroelectrics; X-ray detection
Categories
Funding
- National Key Research and Development Program of China [2017YFA0204800]
- Key Program project of the National Natural Science Foundation of China [51933010]
- National Natural Science Foundation of China [61974085]
- National University Research Fund [GK201802005]
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This study demonstrates the integration of ferroelectricity and X-ray detection property in hybrid bromide double perovskites for the first time. The authors successfully developed a novel lead-free iodide double perovskite for high-performance X-ray sensitive ferroelectric devices, showing promising X-ray response and excellent ferroelectric properties.
Ferroelectricity and X-ray detection property have been recently implemented for the first time in hybrid bromide double perovskites. It sheds a light on achieving photosensitive and ferroelectric multifunctional materials based on 2D lead-free hybrid halide double perovskites. However, the low T-c, small P-s, and relatively low X-ray sensitivity in the reported bromide double perovskites hinder practical applications. Herein, the authors demonstrate a novel 2D lead-free iodide double perovskite (4,4-difluoropiperidinium)(4)AgBiI8 (1) for high-performance X-ray sensitive ferroelectric devices. Centimeter-sized single crystal of 1 is obtained and exhibits an excellent ferroelectricity including a high T-c up to 422 K and a large P-s of 10.5 mu C cm(-2). Moreover, due to a large X-ray attenuation and efficient charge carrier mobility (mu)-charge carrier lifetime (tau) product, the crystal 1 also exhibits promising X-ray response with a high sensitivity up to 188 mu C center dot Gy(air)(-1) cm(-2) and a detection limit below 3.13 mu Gy(air)center dot s(-1). Therefore, this finding is a step further toward practical applications of lead-free halide perovskite in high-performance photoelectronic devices. It will afford a promising platform for exploring novel photosensitive ferroelectric multifunctional materials based on lead-free double perovskites.
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