Pulse Electrodeposition of a Superhydrophilic and Binder-Free Ni- Fe-P Nanostructure as Highly Active and Durable Electrocatalyst for Both Hydrogen and Oxygen Evolution Reactions

Development and fabrication of electrodes with favorable electrocatalytic activity, low-cost, and excellent electrocatalytic durability are one of the most important issues in the hydrogen production area using the electrochemical water splitting process. We use the pulse electrodeposition method as a versatile and cost-effective approach to synthesize three-dimensional Ni-Fe-P electrocatalysts on nickel nanostructures under various applied frequencies and duration times, in which nanostructures exhibit excellent intrinsic electrocatalytic activity. Benefiting from the three-dimensional structure, as well as the simultaneous presence of the three elements nickel, iron, and phosphorus, the electrode fabricated at the optimal conditions has indicated outstanding electrocatalytic activity with a eta(10) of 66 and 198 mV for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively, in a 1.0 M KOH solution. Also, the water electrolysis cell constructed with this electrode and tested as a bifunctional electrode exhibited 1.508 V for 10 mA cm(-2) in overall water splitting. In addition, the lowest amount of potential change in 100 mA cm(-2 )was observed for HER and OER, indicating excellent electrocatalytic stability. This study proposes a binder-free and economical technique for the synthesis of three-dimensional electrocatalysts.