Bifunctional Regenerated Cellulose/Polyaniline/Nanosilver Fibers as a Catalyst/Bactericide for Water Decontamination

For antagonizing urgent water pollution and increasing environmental consciousness, the integration of renewable resources and nanotechnologies has become a trend to improve water quality in the ecosystem. Here, we designed a green route to fabricate regenerated cellulose fibers (CFs) with 3D micro- and nanoporous structures in NaOH/urea aqueous solvent systems via a scalable wet-spinning procedure as support materials for nanoparticles (NPs). Modification of CFs with polyaniline@Ag nanocomposites through in situ reduction of the silver ion with aqueous aniline led to enhanced pollutant removal efficiency of functional cellulose-based fibers (FCFs), demonstrating both rapid hydrogenation catalytic performance for the reduction of p-nitrophenol and high antibacterial properties for in-flow water purification. Most importantly, the hierarchically porous structures of FCFs not only provided carrier space but also formed a limiting domain guaranteeing the homogeneity of FCFs even with a Ag NP content as high as 36.47 wt %. The prepared functional fibers show good behavior in in-flow water purification, representing significant advancement in the use of biomass fibers for catalytic and bactericidal applications in liquid media.

Automated summary

Through a green approach, regenerated cellulose fibers with nanostructured pores were designed and manufactured, showing potential in improving water pollution treatment efficiency through the combination of nanotechnologies, demonstrating their potential in catalytic and bactericidal applications.