Journal
ACS APPLIED ENERGY MATERIALS
Volume 3, Issue 10, Pages 9848-9855Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c01545
Keywords
Fused Porphyrins; Chemical Vapor Deposition; Hydrogen Evolution Reaction; Heterogeneous Catalysis; Photocatalysis
Funding
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program [865985]
- Luxembourg National Research Fund (FNR) through the project PLASPEROX [19/13711983]
- European Research Council (ERC) [865985] Funding Source: European Research Council (ERC)
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Metalloporphyrin-based photocatalysts have attracted great interest due to their high extinction coefficient in the visible range coupled to a catalytically active central metal ion surrounded by a highly conjugated heterocyclic macrocycle. In this work, fused copper(II) porphyrin-based conjugated polymer thin films are shown to be active electrocatalysts and photocatalysts for the heterogeneous hydrogen evolution reaction (HER). The fused copper(II) porphyrin thin films notably show a significant reduction of the overpotential required for HER in comparison to the reference nonfused porphyrin thin films. More importantly, in-depth high-resolution mass spectrometry reveals how the porphyrin substituents influence the catalytic performance of the films, with phenyl substituents enabling superior photocatalytic performances over mesityl substituents, providing insights for the engineering of heterogeneous catalysts based on fused metalloporphyrins.
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