4.6 Article

π-Extended Tetraphenylethylene Containing a Dicyanovinyl Group as an Ideal Fluorescence Turn-On and Naked-Eye Color Change Probe for Hydrazine Detection

Journal

ACS OMEGA
Volume 5, Issue 43, Pages 28369-28374

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c04370

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Funding

  1. Korean National Research Foundation (NRF) [2018R1C1B6006110]
  2. National Research Foundation of Korea [2018R1C1B6006110] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A pi-extended tetraphenylethylene derivative 1 was developed as a fluorescent turn-on and naked-eye color change probe for hydrazine detection. Probe 1 was composed of the representative AIE luminogen (AIEgen), tetraphenylethylene, and a dicyanovinyl group was adopted for hydrazine recognition. Upon exposure of hydrazine, probe 1 immediately gave a significant aggregation-induced emission around 575 nm and excellent photostability. A naked-eye color change was also observed from red to yellow. Moreover, probe 1 was simply coated with a glass-backed silica gelcoated thin-layer chromatography plate, showing rapid and on-site detection of hydrazine vapor.

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