Journal
ACS OMEGA
Volume 5, Issue 35, Pages 22314-22324Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c02671
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Classical cyclophanes with two benzene rings have been compared with cyclophanes with one benzene ring replaced with an aliphatic part and aliphatic compounds, which are cyclophane analogues. Analysis of geometry, atomic charges, and aromatic and steric energy and investigation of intramolecular noncovalent interactions and charge mobility show that there is no special feature that distinguishes the classical cyclophanes from aliphatic analogues, so the definition of cyclophanes can be extended to other compounds.
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