Journal
MOLECULAR CATALYSIS
Volume 493, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2020.111084
Keywords
Linoleic acid; Heteropolyacids; Tungsten catalyst; Hydrogen peroxide; THF derivatives
Categories
Funding
- French Ministry of National Education, Higher Education and Research
- France-Canada Research Fund
- Region Nouvelle Aquitaine (FR CNRS INCREASE 3707, TECHNO-GREEN, FEDER)
Ask authors/readers for more resources
The synthesis of THF and tetrahydro-2H-pyrane is of interest due to the applications of such molecules as antitumour, pesticidal, antiprotozoal and antimicrobial agents for instance. Here, an original approach was performed to prepare these derivatives starting from linoleic acid in the presence of hydrogen peroxide and phosphotungstic acid in the absence of a phase transfer agent. A maximum cyclic compounds yield of 99 % was obtained under mild conditions of temperature. A heterogeneous catalyst was synthesized by exchanging proton by Cs to obtain Cs2.3H0.7PW12O40, that was recycled up to 3 cycles. It is one of the best yield to these products observed in the literature from fatty acids.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available