Journal
MOLECULAR CATALYSIS
Volume 494, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2020.111120
Keywords
Copper catalysis; Chitosan supported catalyst; Phosphoryl azide; Aliphatic alcohol; Alkyl/aryl mixed phosphate; Esterification
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Funding
- National Key R&D Program of China [2018YFB0604603]
- National Natural Science Foundation of China [NSFC: 21606182, 21901150]
- Natural Science Basic Research Program of Shaanxi -Shaanxi Coal and Chemical Industry Joint Foundation [2019JLM-20]
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An efficient methodology was established for the preparation of alkyl/aryl mixed phosphates under aerobic conditions promoted by a easily recoverable heterogeneous catalyst. This highly active copper catalyst was obtained by directly mixing of copper precursor with chitosan solution, followed by a simple work-up process. In this catalytic system, different phosphoryl azides and aliphatic alcohols were employed to generate desired products in moderate to excellent yields with good functional group tolerance. This protocol provided a practical application of the chitosan supported heterogeneous copper catalyst towards a novel P-O bond formation.
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