Journal
NANOMATERIALS
Volume 10, Issue 11, Pages -Publisher
MDPI
DOI: 10.3390/nano10112111
Keywords
magnetic catalyst; core-shell; iron; magnetic nanoparticles; alcohol oxidation; alcohol dehydration; sonochemistry; microwave; ultrasound; mechanochemistry
Categories
Funding
- Fundacao para a Ciencia e Tecnologia [UIDB/00100/2020, UIDB/04565/2020]
- Instituto Superior Tecnico for the Scientific Employment [IST-ID/119/2018]
- FCT [SFRH/BD/146426/2019]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/146426/2019] Funding Source: FCT
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For the first time, herein is reported the use of a magnetic core-shell support for a C-scorpionate metallic complex. The prepared hybrid material, that consists on the C-scorpionate iron(II) complex [FeCl2{kappa(3)-HC(pz)(3)}] (pz, pyrazolyl) immobilized at magnetic core-shell particles (Fe3O4/TiO2), was tested as catalyst for the oxidation of secondary alcohols using the model substrate 1-phenylethanol. Moreover, the application of alternative energy sources (e.g., ultrasounds, microwaves, mechanical or thermal) for the peroxidative alcohol oxidation using the magnetic heterogenized iron(II) scorpionate led to different/unusual outcomes that are presented and discussed.
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