4.6 Review

Surfactant-free microemulsions

Journal

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE
Volume 25, Issue -, Pages 67-74

Publisher

ELSEVIER SCIENCE LONDON
DOI: 10.1016/j.cocis.2016.06.013

Keywords

Microemulsion; Surfactant-free microemulsion; Colloid; Phase behavior; Conductivity

Funding

  1. National Natural Science Foundation of China [21403121, 21573133]
  2. Natural Science Foundation of Shandong Province of China [ZR2013BQ013]
  3. Project of Higher Educational Science and Technology of Shandong Province of China [J14LC13]

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Surfactants (or amphiphiles) are generally believed to be a necessary component of microemulsions. However, research has found that in the absence of traditional surfactants, microemulsions can also form in a ternary system of two immiscible fluids and an amphi-solvent. Such microemulsions are called surfactant-free microemulsions (SFMEs). The so-called amphi-solvent is a solvent that is completely or at least partially miscible with each of the two immiscible fluids. The structures and properties of SFMEs are similar to those of traditional surfactant-based microemulsions (SBMEs) to some extent This review focuses on recent advances in SFMEs, including their phase behavior, structures, properties and potential applications. (C) 2016 Elsevier Ltd. All rights reserved.

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