Journal
FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING
Volume 15, Issue 4, Pages -Publisher
HIGHER EDUCATION PRESS
DOI: 10.1007/s11783-020-1350-x
Keywords
Coagulation; Polytitanium chloride; Coagulation behaviour; Algae; Floc property
Categories
Funding
- National Natural Science Foundation of China [51978311]
- Shandong Provincial Natural Science Foundation, China [ZR2019BEE044]
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Titanium-based coagulation has been proven effective for purifying micro-polluted water containing algae, with the presence of algae enhancing the removal of organic matter. The study found that polytitanium coagulation is highly effective in separating algae from surface water, even achieving up to 98% removal. The presence of algae in water can assist polytitanium coagulation by acting as an additional coagulant or flocculation aid.
Titanium-based coagulation has proved to be effective for algae-laden micro-polluted water purification processes. However, the influence of algae inclusion in surface water treatment by titanium coagulation is barely reported. This study reports the influence of both Microcystis aeruginosa and Microcystis wesenbergii in surface water during polytitanium coagulation. Jar tests were performed to evaluate coagulation performance using both algae-free (controlled) and algae-laden water samples, and floc properties were studied using a laser diffraction particle size analyzer for online monitoring. Results show that polytitanium coagulation can be highly effective in algae separation, removing up to 98% from surface water. Additionally, the presence of algae enhanced organic matter removal by up to 30% compared to controlled water containing only organic matter. Polytitanium coagulation achieved significant removal of fluorescent organic materials and organic matter with a wide range of molecular weight distribution (693-4945 Da) even in the presence of algae species in surface water. The presence of algae cells and/or algal organic matter is likely to function as an additional coagulant or flocculation aid, assisting polytitanium coagulation through adsorption and bridging effects. Although the dominant coagulation mechanisms with polytitanium coagulant were influenced by the coagulant dosage and initial solution pH, algae species in surface water could enhance the charge neutralization capability of the polytitanium coagulant. Algae-rich flocs were also more prone to breakage with strength factors approximately 10% lower than those of algae-free flocs. Loose structure of the flocs will require careful handling of the flocs during coagulation-sedimentation-filtration processes. (c) Higher Education Press 2020
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