Journal
ADVANCED ENERGY MATERIALS
Volume 10, Issue 42, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202002602
Keywords
CO(2)reduction; light-to-fuel efficiency; NiCo; Co-Al(2)O(3)nanocomposites; photocatalytic; photothermocatalytic
Categories
Funding
- National Natural Science Foundation of China [21972109, 21673168]
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Unique nanocomposites of NiCo alloy nanoparticles with Ni/Co molar ratios of 1.86, 1.60, and 0.38 supported on Co-doped Al(2)O(3)nanosheets are prepared by a facile approach. Very high fuel production rates of CO (r(CO)) and H-2(r(H2)) (70.53 and 63.46 mmol min(-1)g(-1)) and light-to-fuel efficiency (eta, 29.7%) are achieved via photothermocatalytic CO(2)reduction by methane (CRM) on Ni1.60Co/Co-Al(2)O(3)simply utilizing focused UV-visible-infrared (UV-vis-IR) illumination. Ni1.60Co/Co-Al(2)O(3)also demonstrates highr(CO)andr(H2)values (50.99 and 39.72 mmol min(-1)g(-1)) as well as high eta value (26.3%) under lambda > 560 nm focused vis-IR illumination. The high photothermocatalytic activity is derived from the light-driven thermocatalytic CRM. A novel photoactivation is found to substantially promote the light-driven thermocatalytic CRM due to the apparent activation energy being considerably reduced upon illumination. It is found that the Ni/Co molar ratio in the NiCo/Co-Al(2)O(3)samples has an important effect on the photothermocatalytic durability. The samples of Ni1.60Co/Co-Al(2)O(3)and Ni1.86Co/Co-Al(2)O(3)with a higher Ni/Co molar ratio demonstrate excellent photothermocatalytic durability, while the Ni0.38Co/Co-Al(2)O(3)with a lower Ni/Co molar ratio has less durability. This is attributed to carbon deposition rate being significantly reduced on Ni1.60Co/Co-Al(2)O(3)and Ni1.86Co/Co-Al(2)O(3)as compared to its single metal counterparts.
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