Journal
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume 30, Issue 9, Pages 2413-2423Publisher
ELSEVIER
DOI: 10.1016/S1003-6326(20)65388-2
Keywords
Mg-Li alloy; corrosion resistance; surface film; electrochemical testing; in-situ electrochemical-Raman spectroscopy
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Funding
- National Natural Science Foundation of China [51901047, 51801029]
- National College Students Innovation and Entrepreneurship Training Program, China [201911845185, xj201911845345]
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To study different corrosion resistances and surface film types of hexagonal close-packed (HCP) pure Mg and body-centered cubic (BCC) Mg-14wt.%Li alloy in 0.1 mol/L NaCl, a series of experiments were conducted, including hydrogen evolution, mass loss, in-situ electrochemical testing combined with Raman spectroscopy and microstructural observation. The results indicate that the corrosion resistance of pure Mg is superior to that of Mg-14Li, and the protective function of the surface films on both magnesium systems is elevated within 16 h of immersion in 0.1 mol/L NaCl. An articulated, thick, and needle-like surface film containing Li2CO3 on Mg-14Li, different from the typically thin, flaky Mg(OH)(2) film on pure Mg, is confirmed via scanning electron microscopy (SEM). However, both surface films can be broken down at a high anodic over-potential. Thus, different corrosion resistances of the two Mg systems are ascribed to various protective films forming on their surfaces.
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