Journal
SYNLETT
Volume 32, Issue 6, Pages 539-544Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1277-8669
Keywords
iodonium catalysis; olefin oxyamination; regioselective; N-heterocycles; oxazolines; aminooxygenation
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Funding
- National Institute of General Medical Sciences of the National Institutes of Health [R15GM139156]
- University of Toledo
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Iodonium catalysis is used in this study for intermolecular olefin oxyamination reaction, where urea is employed as the O- and N-source for regioselective addition onto both activated and unactivated alkenes. Mechanistic studies have confirmed the presence of an iodonium intermediate.
Iodonium catalysis is described here to accomplish an intermolecular olefin oxyamination reaction. Urea is used as the O- and N-source to add across both activated and unactivated alkenes in a regioselective manner. Mechanistic studies confirm the presence of an iodonium intermediate.
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