4.7 Article

Amino group decorated coordination polymers for enhanced detection of folic

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2020.118443

Keywords

Coordination polymer; Fluorescent; Chemosensors; Folic acid

Categories

Funding

  1. National Natural Science Foundation of China [31860192, 21701035, 21961004]
  2. specific research project of Guangxi for research bases and talents [AD18126005, AD 18126002]
  3. Natural Science Foundation of Guangxi Province [2018GXNSFAA138129, 2018GXNSFAA138126]
  4. foundation ability enhancement project of young teachers in Guangxi universities [2018KY0173, 2018KY0163]

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A series of fluorescent coordination polymers (CPs) {[Cd-2(CH3-bpeb)(2)(BDC)(2)] CP1, (BDC)(0.5)/(NH2-BDC)(0.5)-CP1, (BDC)(0.34)/(NH2-BDC)(0.66)-CP1, (BDC)(0.25)/(NH2-BDC)(0.75)-CP1, (BDC)(0.2)/(NH2-BDC)(0.8)-CP1, (NH2-BDC)-CP1} were prepared from conjugated ligand 4,4'-((2-methyl-1,4-phenylene)bis(ethene-2,1-diyl))bipyridine (CH3-bpeb), terephthalic acid (BDC), aminoterephthalic acid (NH2-BDC) and CdSO4 under solvothermal conditions. The fluorescence of aqueous suspensions of these CPswas quenched by folic acid (FA) in a concentration dependentmanner. The efficiency of quenching increasingwith an increased proportion of NH2-BDC ligand in the CPwith (NH2BDC)-CP1 exhibiting a low detection limit of 1.7 x 10(-7) M. (C) 2020 Published by Elsevier B.V.

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