Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 318, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2020.128242
Keywords
Nonenzymatic sensor; Co,N-doped composite; Self-supporting electrode; Hydrogen peroxide; Metal-organic frameworks
Funding
- National Natural Science Foundation of China [21675147, 21974097]
- Ministry of Science and Technology of China [2016YFC1400601]
- Jilin Provincial Science and Technology Development Program [20190201242JC]
- Science and Technology Bureau of Jiangmen [2019030102360012639]
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In this work, self-supporting hierarchical Co-embedded N-doped carbon structures composed of leaf-like carbon sheets arrays and interconnected carbon nanotubes (CNTs) were synthesized on carbon cloth (CC) via dicyandiamide-assisted pyrolysis. The resultant composite is abbreviated as CC/Co@C-CNTs, in which Co nanoparticles are embedded both in carbon sheets and the tips of CNTs. The characterizations proved the hierarchical three-dimensional structure, large electroactive surface area of 4.71 cm(-2), fast electron transfer, abundant Co/Co-N-x active sites, and synergistic effect between Co/Co-Nx species and CNTs in the CC/Co@C-CNTs-800-0.10 electrocatalyst. Benefiting from these unique superiorities, the CC/Co@C-CNTs-800-0.10 freestanding electrode exhibits excellent sensing performances of H2O2. It possesses a high sensitivity (388 mu A mM(-1) cm(-2)), fast response within 4 s, low detection limit (0.27 mu M, S/N = 3) and wide linear range (0.40 mu M-7.2 mM). More importantly, the freestanding electrode can be used to in situ detect H2O2 released from MDA-MB-231 cells and HeLa cells. This work provides a new design of nonenzymatic electrochemical sensing platform for amperometric determination of H2O2 in biological environment, which has great potential in cancer diagnosis, environmental monitoring and food analysis.
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