Journal
CRYSTENGCOMM
Volume 18, Issue 41, Pages 7950-7954Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce01540a
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Funding
- Ministerio de Ciencia e Innovacion (Spain) (Project CONSOLIDER-INGENIO SUPRAMED) [CSD 2010-00065]
- Ministerio de Economia y Competitividad (MINECO)
- FEDER funds [CTQ2013-46275-P]
- Unidad de Excelencia Maria de Maeztu [MdM-2015-0538]
- Generalitat Valenciana [PROMETEO/2016/147]
- Ministerio de Economia y Competitividad (Spain)
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A new octacoordinated Fe(II) compound, [(FeLN4)-L-II()(2)](BPh4)(2)center dot 3CH(2)Cl(2), as an example of the scarce FeN8 systems, has been isolated with a tetradentate triazolopyridine-based ligand from a solution containing the related hexacoordinated [FeII(LN3)(2)](2+) complex, with L-N3 = pyridyltriazolo-pyridyl-bromopyrimidine and L-N4 = bis(pyridyltriazolo-pyridine).
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