4.7 Article

Thermal expansion properties of three isostructural co-crystals composed of isosteric components: interplay between halogen and hydrogen bonds

Journal

CRYSTENGCOMM
Volume 18, Issue 43, Pages 8354-8357

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce01674j

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Funding

  1. National Science Foundation [DMR-1408834]
  2. Webster University
  3. Faculty Research Grant
  4. Faculty Development Fund

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Co-crystallization of a symmetrical azo bipyridine with isosteric resorcinols affords isostructural co-crystals that exhibit linear thermal expansion along each axis. The thermal expansions involve interplay between intra-layer halogen and hydrogen bonds.

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