Journal
CRYSTENGCOMM
Volume 18, Issue 27, Pages 5089-5094Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce00610h
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Funding
- Kerala State Council for Science, Technology and Environment (KSCSTE) [007/KSYSA-RG/2014/KSCSTE]
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We report the synthesis, X-ray structures and photophysical properties of a few benzoylpyrene (BP) derivatives. Steric hindrance due to incremental benzoyl groups causes a systematic reduction in the orbital overlap (pi-pi) between vicinal pyrene units affording green-yellow-orange solid-state emitters. Crystallization induced emission could arise from: i) electronic (dipolar/excitonic) interactions, ii) arrested bond rotations, and/or iii) lack of solvation in crystalline 1-4BP (Phi(Fl) similar to 2-26%) when compared to that in solution (Phi(Fl) <= 1%). Our earlier effort [Chem. Commun. 2014, 50, 8644] on progressive acylation, in contrast to benzoylation, results in a gradual increase in the pi-pi overlap between vicinal pyrenes.
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