4.0 Article

Synthesis of Pyrrolo[2,1-c][1,4]oxazine-1,6,7-triones by the Reaction of 3-Methylenemorpholin-2-ones with Oxalyl Chloride

Journal

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 56, Issue 8, Pages 1367-1373

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428020080060

Keywords

enaminoketone; 3-methylenemorpholin-2-one; pyrroloxazinetrione; oxalyl chloride; hetareno[e]pyrrole; 4-hetarylfurandione; X-ray diffraction

Funding

  1. Russian Foundation for Basic Research [19-33-90222]
  2. Government of the Perm Krai

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(Z)-3-(2-Aryl-2-oxoethylidene)morpholin-2-ones were synthesized by the reaction of aroylpyruvic acids with ethanolamine or 2-propanolamine. The products reacted with oxalyl chloride to form 8-aroyl-3,4-dihydropyrrolo[2,1-c][1,4]oxazin-1,6,7(1H)-triones.

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