4.7 Article

Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

Journal

CRYSTENGCOMM
Volume 18, Issue 22, Pages 4018-4022

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce02462e

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Funding

  1. NanoNextNL
  2. micro and nanotechnology consortium of the Government of the Netherlands
  3. European Research Council under the European Union's Seventh Framework Programme (FP)
  4. ERC Grant [335746]
  5. CrystEng-MOF-MMM

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A study of a copper-based metal-organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4',4 ''-s-triazine-2,4,6-triyl-tribenzoic acid (H(3)TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

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