Journal
CRYSTENGCOMM
Volume 18, Issue 35, Pages 6689-6699Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce01126h
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Funding
- Ministry of Education and Science of the Russian Federation [K2-2015-001, 11.1077.2014/K]
- Russian Foundation for Basic Research [16-08-00957/16]
- MANA-NIMS
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A rich variety of hollow and solid (without internal hollow spaces) spherical boron oxynitride nanoparticles (BNO-NPs) with smooth or petalled surfaces were synthesized during a boron oxide-assisted chemical vapour deposition (BOCVD) process. Diverse BNO-NPs were obtained while utilizing different precursors, gas flow rates and synthesis temperatures in the range of 1200-1430 degrees C. The BNO-NP morphologies, atomic structures and spatially-resolved chemical compositions were studied by scanning (SEM) and transmission electron microscopy (TEM), X-ray diffraction (XRD), energy-dispersive X-ray, Fourier-transform infrared and confocal Raman spectroscopy. Particle size distributions were measured using dynamic light scattering under visual microscopic control. A growth model of different spherical BNO-NP types based on the detailed analysis of physical-chemical processes at different BOCVD stages was proposed. A new type of spherical BNO-NPs of hedgehog morphologies with BN nanowires on their surfaces was first predicted in accordance with the designed model and then experimentally verified.
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