Journal
CRYSTENGCOMM
Volume 18, Issue 26, Pages 4900-4904Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce00204h
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Funding
- National Natural Science Foundation of China [21332008, 21402210, 91527301]
- National Basic Research Program [2015CB856502]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12010400]
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Complexation between a triptycene-derived macrotricyclic host and paraquat derivative and different polycyclic aromatic hydrocarbons in the solid state was investigated in detail. It was found that through multiple pi-pi, C-H center dot center dot center dot pi and C-H center dot center dot center dot O hydrogen bonding interactions, four new kinds of quaternary complexes with Russian doll-like capsule structures in different complexation modes can be obtained. Furthermore, the complexes could self-assemble into linear supramolecular arrays, and 2D grid-like structures.
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