Journal
CRYSTAL GROWTH & DESIGN
Volume 16, Issue 10, Pages 5598-5602Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.6b01115
Keywords
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Funding
- Spanish MINECO [PN MAT2012-30994]
- Catalan AGAUR [2014 SGR 80]
- MINECO [RYC-2010-06530]
- Generalitat de Catalunya
- Spanish MINECO through the Severo Ochoa Centers of Excellence Program [SEV-2013-0295]
- ICREA Funding Source: Custom
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The synthesis, X-ray crystallographic structure, and Water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu2+) are shown. This coordination polymer is made by connecting paddle-wheel Cu2+ units through a gamma-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.
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