Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 195, Issue 11, Pages 905-909Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2020.1804150
Keywords
Diazadiphosphapentalenes; cyclotetraphosphanes; phosphinidenes; masked phosphinidenes; azaphospholes
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Funding
- Russian Science Foundation [19-13-00400] Funding Source: Russian Science Foundation
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This review article provides the reader with numerous evidence that 3a,6a-diaza-1,4-diphosphapentalenes are a form of existence of stabilized singlet phosphinidenes. In particular, the oligomerization reactions, addition at the phosphorus atom, and an unusual type of coordination with metals and Lewis acids testify to this.
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