Journal
ORGANIC LETTERS
Volume 22, Issue 19, Pages 7635-7639Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02832
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Funding
- National Natural Science Foundation of China [21871160, 21672121]
- National Thousand Plan Youth Program of China
- National Ten Thousand Plan (Leading Talents) of China
- Innovation Promotion Program of Ministry of Science & Technology (China),Tsinghua University
- Bayer Investigator Fellow Award
- Fellowship of Tsinghua-Peking Centre for Life Sciences (CLS)
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The unprecedented enantioselective NHC-catalyzed [3 + 3] annulation of alpha-bromoenals with amidines via a dual C-N bond formation is described. The protocol allows a rapid preparation of 5,6-dihydropyrimidinones in acceptable yields with good enantioselectivities.
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