4.8 Article

Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene

Journal

ORGANIC LETTERS
Volume 22, Issue 18, Pages 7397-7402

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02754

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Funding

  1. National Natural Science Foundation of China [21672026, 21971020]

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The selective fusions with pyrene derivative to the rim and flank bonds of corannulene generated 4 and 7, respectively, which underwent a Scholl reaction to provide novel distorted PAHs CORA-1 and CORA-2, consisting of corannulene and dibenzocoronene units with different connections between them. The studies revealed that the properties of these PAHs are highly dependent on the fusing positions of corannulene.

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