Journal
ORGANIC LETTERS
Volume 22, Issue 20, Pages 7942-7946Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02846
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Funding
- National Natural Science Foundation of China [51603088]
- Natural Science Foundation of Jiangsu Province, China [BK20150154]
- K. C. Wong Magna Fund in Ningbo University
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One-pot synthesis of a new doubly boron-doped polycyclic aromatic hydrocarbon of 6,12-dimesityl-6,12-dihydro-6,12-diboradibenzo[def,mno]chrysene (MDBDBC) was reported. MDBDBC features a rigid planar electron-deficient core structure and demonstrates good chemical and thermal stabilities. A low-lying LUMO of -3.53 eV, a low locally excited triplet energy of 1.92 eV, as well as green electroluminescence with maximum EQE of 4.9% were found for MDBDBC, suggesting its potential as an n-type unit for future organic light emitting diode applications.
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