Journal
ORGANIC LETTERS
Volume 22, Issue 20, Pages 8055-8058Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03005
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Funding
- National Institutes of Health
- NIHGMS [1R01GM124089]
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The synthesis of alpha-pyrazole and alpha-triazole derivatives of ketones by the ceric ammonium nitrate-mediated oxidative coupling of enolsilanes with heteroarenes is reported. The reaction proceeds under mild reaction conditions to provide a diversity of products, including sterically hindered fully substituted derivatives.
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