Journal
ORGANIC LETTERS
Volume 22, Issue 20, Pages 7874-7878Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02778
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Funding
- National Natural Science Foundation of China [21772046, 2193103]
- Subsidized Project for Cultivating Postgraduates' Innovative Ability in Scientific Research of Huaqiao University
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An important framework of o-amino benzofuranthioethers was constructed by Cu-catalyzed arylative cyclization of N-tosylhydrazone-bearing thiocarbamates with silylaryl triflates or ArI. This transformation provides a novel strategy for the synthesis of valuable arylative o-amino benzofuranthioethers in moderate yields which could not be obtained from known methods. The reaction features smart design, efficient construction, and mild reaction conditions.
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