Journal
MOLECULES
Volume 25, Issue 21, Pages -Publisher
MDPI
DOI: 10.3390/molecules25214943
Keywords
carbone complexes; carbido complexes; transition metal complexes; chemical bonding
Funding
- Deutsche Forschungsgemeinschaft
- Nanjing Tech University [39837132, 39837123]
- National Natural Science Foundation of China [21703099, 21993044]
- Natural Science Foundation of Jiangsu Province for Youth [BK20170964]
- SICAM Fellowship from Jiangsu National Synergetic Innovation Center for Advanced Materials
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This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (sigma and pi) donation to the metal atom [M]paired left arrows CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 -> [M]-CR2 -> [M]-CR -> [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.
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